Belgian Segaert won his first ever stage on a Grand Tour after making a charge for the line with just over three kilometres remaining in an eventful stage.
The 23-year-old Bahrain Victorious rider prevailed in Novi Ligure in an eventful 175km stage from Imperia which saw key sprint rivals Jonathan Milan and Paul Magnier dropped on the final Bric Berton climb.
Portuguese Eulalio extended his lead over pre-race favourite Jonas Vingegaard to 33 seconds after claiming intermediate sprint points.
In the early part of the stage several attacks pulled away before being clawed back by the peloton, until a six-man group, none contending any of the jerseys on offer, created a gap of two minutes before the Colle Giovo climb.
That sweeping climb, which ended with the break caught, came around 80km from a finish which looked perfect for the sprinters.
Two of those sprint contenders, France’s Paul Magnier and home hope Jonathan Milan, drifted off the back of the peloton near the crest of the subsequent Bric Berton climb where the steep gradient put the non-climbers to the test.
Milan and Magnier could not close the gap on a rapid peloton and ended up finishing several minutes off the pace.
But it was not to be a sprinter’s finish thanks to Segaert’s bold burst which made it perfect day for his team.
On Friday the peloton will take on a largely flat run between Alessandria and Verbania which features two punchy climbs towards the end of the 189km stage.
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